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Beilstein J. Org. Chem. 2017, 13, 2663–2670, doi:10.3762/bjoc.13.264
Graphical Abstract
Figure 1: Structure of an azlactone dimer.
Scheme 1: Diastereoselective dimerization of azlactones. Reactions were carried out using 0.45 mmol of 1 and ...
Figure 2: X-ray crystallographic structure of 2a (30% ellipsoids probability).
Scheme 2: Sterically bulky azlactone enol derivatives.
Figure 3: Plausible mechanism for the dimerization of azlactone.
Figure 4: Plot of vs time for the dimerization of azlactone 1a.
Scheme 3: Reduction of 2c.
Figure 5: X-ray crystallographic structure of 6 (30% ellipsoids probability).